4020-99-9, Name is Methoxydiphenylphosphine, molecular formula is C13H13OP, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 4020-99-9, Computed Properties of C13H13OP
Geometrical isomerization of fac-Mo(CO)3L3 (L = P(OPh)3, P(OMe)3, P(OEt)3) to the mer form and that of cis-Mo(CO)4L2 (L = P(OPh)3, P(OMe)3, PPh2(OMe)) to the trans form were observed in CH2Cl2 at room temperature in the presence of a catalytic amount of Me3SiOSO2CF3 (TMSOTf). Crossover experiments suggest that a ligand dissociation is not involved in the isomerization. A catalytic cycle involving an interaction of the silicon atom in Me3Si+ with one oxygen in P(OR)3 ligands has been proposed. The first isolation and the X-ray structure analysis were attained for mer-Mo(CO)3{P(OPh)3}3 through the TSMOTf-assisted isomerization of fac-Mo(CO)3{P(OPh)3}3.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C13H13OP. In my other articles, you can also check out more blogs about 4020-99-9
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate