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A phosphite antioxidant preparation method (by machine translation)
A phosphite antioxidant preparation method, comprises the following steps: 1) preparation of organic magnesium compound solution: the cutting is added to the reactor, and the atmosphere in the reactor to access protection, iodize iodine vapor simple substance until the reactor is full, and then to a reactor by adding 4, 4 – dibromo biphenyl solution and heating to reflux, after dropping drip and the organic solvent is added to the reaction system and clarification, the reflow state reaction 2 – 6h, cooling; 2) for – 15 – 20 C under, the above-mentioned organic magnesium compound solution is dropped to add to the dual (2, 4 – di-tert-butyl phenyl) sub-chloride in the solution, and milling after – 10 – 50 C lower heat insulating 1 – 5h, through filtering, washing, the filtrate, filtering, to obtain the magnesium salt solid and filtrate, removing the solvent in the filtrate, getting the wet white powder, then isopropyl alcohol, and then the powder dry. The technique of the invention is mild, simple operation, high catalyst selectivity, the product yield is high, the reaction solvent can be recovered, and environmental protection. (by machine translation)
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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate