Category: 2622-14-2

2622-14-2, Tricyclohexylphosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

General procedure: Reactions for each substrate were run in triplicate. For substrate oxidation reactions, either 21 mg pyridine-N-oxide (220 mumol) or 27 mg of x-PVP-N-oxide (220 mumol) was added to 100 mumol of substrate in 500 muL of acetonitrile in a J-Young NMR tube and sealed in the glovebox. The reactions were taken out of the glovebox and heated at 110 C for 24 hours. After cooling to room temperature, the solvent was transferred to a clean vial and 100 muL of a 0.333 M of 2-adamantanone solution in chloroform was added as an internal standard. The solution volume was diluted to 2.0 mL with chloroform, filtered, and analyzed by GC/FID. Product peaks were identified by comparison to GC/FID chromatograms of authentic samples of the expected products, and percent conversions were determined by comparison to 2-adamantanone as a standard., 2622-14-2

Big data shows that 2622-14-2 is playing an increasingly important role.

Reference£º
Article; Bauer, Anna M.; Ramey, Erin E.; Oberle, Kjersti G.; Fata, Gretchen A.; Hutchison, Chloe D.; Turlington, Christopher R.; Tetrahedron Letters; vol. 60; 43; (2019);,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate

2622-14-2, Tricyclohexylphosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

General procedure: To a solution of 1 (0.2 mmol) in 2 mL of CH3CN/H2O(v/v = 100/1) was added Selectfluor (71 mg, 0.2 mmol). The mixture was stirred at room temperature for 5-60minutes. After removal of the solvent, the residue was then purified by flash column chromatography on silica gel with petroleum ether/ethyl acetate to give the desired product 2.

As the paragraph descriping shows that 2622-14-2 is playing an increasingly important role.

Reference£º
Article; Chen, Qian; Zeng, Jiekun; Yan, Xinxing; Huang, Yulin; Du, Zhiyun; Zhang, Kun; Wen, Chunxiao; Tetrahedron Letters; vol. 57; 30; (2016); p. 3379 – 3381;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate