13991-08-7, 1,2-Bis(diphenylphosphino)benzene is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
Similar procedure described for 1c was used in the synthesis of 5c by using dppbz instead of dppm to obtain a pale yellow solid. Yield: 94%. 31P-NMR (121.42 MHz, 298 K, CDCl3):62.4 ppm (d, 1J(Rh-P) = 134 Hz). 1H-NMR (300 MHz,298 K, CDCl3): 7.38-6.75 (m, 24H, Ph). ESI-MS(?):501.3 (M?-CO-Ph, calc.: 501.3). IR (KBr, cm-1) 1970,m(C:O); 1103, 1032 (OTf-).
The synthetic route of 13991-08-7 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Arcau, Julia; Ferrer, Montserrat; Aguilo, Elisabet; Rodriguez, Laura; Transition Metal Chemistry; vol. 42; 1; (2017); p. 57 – 67;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate