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Effect of the metal-assisted assembling mode on the redox states of hexaazatriphenylene hexacarbonitrile
(Figure Presented) If the hat fits: The size of the ferrocene coligands used during the self-asssembly of hexaazatriphenylene hexacarbonitrile (hat-(CN)6) with CuI ions determines the coordination mode of the hat-(CN)6 ligand (bipyridine chelation or monodentate CN, see picture). The mode of coordination directly affects the oxidation state and the reduction potentials of the Hat-(CN)6 ligand.
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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate