Sakai, Masaaki et al. published their research in Angewandte Chemie, International Edition in 1998 | CAS: 134484-36-9

(S)-(2′-Methoxy-[1,1′-binaphthalen]-2-yl)diphenylphosphine (cas: 134484-36-9) belongs to chiral phosphine ligands. The synthesis of novel trialkylphosphines can be quite difficult, thereby limiting the scope of their chiral variants. Indeed, very little research on chiral tertiary phosphine-catalyzed asymmetric reactions occurred prior to the year 2000.SDS of cas: 134484-36-9

Rhodium-catalyzed addition of organoboronic acids to aldehydes was written by Sakai, Masaaki;Ueda, Masato;Miyaura, Norio. And the article was included in Angewandte Chemie, International Edition in 1998.SDS of cas: 134484-36-9 This article mentions the following:

The title reaction of RB(OH)2 (R = Ph, p-anisyl, o-, p-tolyl, p-FC6H4, 2,4,6-Me3C6H2, trans-BuCH:CH) with R1CHO (R1 = Ph, p-F3CC6H4, p-NCC6H4, p-AcC6H4, p-BrC6H4, p-tolyl, p-anisyl, 2-furyl, 1-naphthyl, C5H11, C6H11) in the presence of Rh(acac)(CO)2 in aqueous DME gave 31-97% 16 R1RCHOH. In the experiment, the researchers used many compounds, for example, (S)-(2′-Methoxy-[1,1′-binaphthalen]-2-yl)diphenylphosphine (cas: 134484-36-9SDS of cas: 134484-36-9).

(S)-(2′-Methoxy-[1,1′-binaphthalen]-2-yl)diphenylphosphine (cas: 134484-36-9) belongs to chiral phosphine ligands. The synthesis of novel trialkylphosphines can be quite difficult, thereby limiting the scope of their chiral variants. Indeed, very little research on chiral tertiary phosphine-catalyzed asymmetric reactions occurred prior to the year 2000.SDS of cas: 134484-36-9

Referemce:
Phosphine ligand,
Chiral phosphines in nucleophilic organocatalysis