Tanaka, Rie; Noguchi, Keiichi; Tanaka, Ken published the artcile< Rhodium-catalyzed asymmetric reductive cyclization of heteroatom-linked 5-alkynals with heteroatom-substituted acetaldehydes>, Related Products of 139139-86-9, the main research area is heteroatom alkynal acetaldehyde rhodium catalyst asym reductive cyclization.
We have established that a cationic rhodium(I)/H8-BINAP complex catalyzes the asym. reductive cyclization of heteroatom-linked 5-alkynals with heteroatom-substituted acetaldehydes in good yields with outstanding enantioselectivity.
Journal of the American Chemical Society published new progress about Alkynals Role: RCT (Reactant), RACT (Reactant or Reagent). 139139-86-9 belongs to class chiral-phosphine-ligands, and the molecular formula is C44H40P2, Related Products of 139139-86-9.
Referemce:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate