Tewari, Yadu B.; Goldberg, Robert N. published the artcile< Thermodynamics of reactions catalyzed by L-iditol 2-dehydrogenase: The xylose assimilation pathway>, COA of Formula: C21H27N7Na2O14P2, the main research area is iditol dehydrogenase reaction thermodn xylose assimilation.
Apparent equilibrium constants and calorimetric enthalpies of reaction have been measured for the following enzyme-catalyzed (L-iditol 2-dehydrogenase) biochem. reactions in phosphate buffer at pHs near 7.5 and at the temperature 298.15 K D-sorbitol(aq) + NADox(aq) = D-fructose(aq) + NADred(aq), L-iditol(aq) + NADox(aq) = L-sorbose(aq) + NADred(aq), xylitol(aq) + NADox(aq) = D-xylulose(aq) + NADred(aq). Here, NADox is β-nicotinamide-adenine dinucleotide (oxidized form) and NADred is β-nicotinamide-adenine dinucleotide (reduced form). The results are used to calculate equilibrium constants and standard molar enthalpies, entropies, and Gibbs free energies for reference reactions involving specific species. Standard formation properties and standard transformed formation properties of the biochem. reactants are also calculated The thermodn. of the xylose assimilation pathway is summarized.
Journal of Chemical Thermodynamics published new progress about Entropy. 606-68-8 belongs to class chiral-phosphine-ligands, and the molecular formula is C21H27N7Na2O14P2, COA of Formula: C21H27N7Na2O14P2.
Referemce:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate