932710-63-9, 4-(Di-tert-butylphosphino)-N,N-dimethylaniline is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
932710-63-9, The procedure used to prepare 1a was modified by replacing the HgCl2 addition with 0.036 g (0.1 mmol) HgBr2. After 1 week,yellow crystals suitable for X-ray analysis were obtained. Yield:0.036 g, 51% based on Hg(SePh)2.Properties: yellow crystalline substance. Melting point: 183-185C. Anal. Calc. for C44H66Hg2Br2N2P2Se2 (1403.84): Hg, 28.58;Se, 11.25; C, 37.64; H, 4.74; N, 2.00. Found: Hg, 28.54; Se, 11.21;C, 37.58; H, 4.60; N, 1.93%. IR (KBr): 3043 [vs(CAH)]; 2960[vas(CH3)]; 2867 [vs(CH3)]; 1598, 1476, 1447 [vs(CC)]; 1372[v(CAN)]; 1070, 1024 [dip(CCAH)]; 741, 694 [dop(CCAH)]; 509[v(PAC)]; 468 cm1 [dop(CCAC)] (dip and dop = in-plane and outof-plane bending motions, respectively).
As the paragraph descriping shows that 932710-63-9 is playing an increasingly important role.
Reference£º
Article; Stieler, Rafael; Faoro, Eliandro; Cechin, Camila Nunes; Floriano, Luana; Lang, Ernesto Schulz; Journal of Molecular Structure; vol. 1079; (2014); p. 9 – 14;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate