SDS of cas: 1824-94-8. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: (2R,3R,4S,5R,6R)-2-(Hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol, is researched, Molecular C7H14O6, CAS is 1824-94-8, about Influence of acetylation on anomeric effect in methyl glycosides. Author is Gubica, Tomasz; Zimniak, Andrzej; Szeleszczuk, Lukasz; Dabrowska, Kinga; Cyranski, Michal K.; Kanska, Marianna.
In the following research acetylation as an unexplored factor in the anomeric effect in carbohydrate chem. has been examined Crystallog. data for Me glycosides and their acetates have been compared and discussed. Some of the Me glycosides form hydrogen bonding with the participation of acetal oxygen atoms. This seems to have the most significant influence on the structural diagnostic parameters for anomeric effect.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate