The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Tris(triphenylphosphine)chlororhodium(SMILESS: [Rh]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6.P(C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9,cas:14694-95-2) is researched.Formula: C6H9ClO3. The article 《Bidentate Triazolate-Based Ligand System: Synthesis, Coordination Modes, and Cooperative Bond Activation》 in relation to this compound, is published in Organometallics. Let’s take a look at the latest research on this compound (cas:14694-95-2).
The 1,2,3-triazole ring represents a highly attractive and useful platform for ligand synthesis. The authors reveal the design, preparation, and properties of a novel bidentate triazolate-based ligand and its potential in cooperative metal-ligand bond activation. The triazolate system exhibits a multiphase mode of coordination to transition metals, supporting both dimeric and monomeric complexes. The complexes were carefully characterized both in solution and in the solid state. The metal-ligand cooperative potential of the basic triazolate pattern was demonstrated in HCl and H-H bond activation.
From this literature《Bidentate Triazolate-Based Ligand System: Synthesis, Coordination Modes, and Cooperative Bond Activation》,we know some information about this compound(14694-95-2)Reference of Tris(triphenylphosphine)chlororhodium, but this is not all information, there are many literatures related to this compound(14694-95-2).
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate