Jeong, Yeolib; Shin, Minjoong; Seo, Myungeun; Kim, Hyunwoo published an article about the compound: Tris(triphenylphosphine)chlororhodium( cas:14694-95-2,SMILESS:[Rh]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6.P(C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9 ).Electric Literature of C54H45ClP3Rh. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:14694-95-2) through the article.
Stereoselective synthesis of polylactic acid (PLA) was achieved using Ti(IV) complexes. The NO3 ligands prepared from 2,2′-dihydroxybenzophenone and salicylaldehyde derivatives were used to control the stereoselectivity of Ti(IV)-catalyzed polymerization of rac-lactide, in which a substituted ligand provided heterotactic PLA with high stereoselectivity. D. functional theory calculations revealed that the ligand structure is crucial for differentiating reaction pathways, and that the octahedral transition states are stabilized by the preorganized intermediates.
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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate