4020-99-9, Methoxydiphenylphosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
Compound 1 (0.153 mmol) was dissolved in 30 ml of hexane and 2 equivalents of the phosphine (61.8 mg, 0.30 mmol) was added. Thesolution was stirred for 60 min. The reaction mixture was taken to dryness under vacuum and the residue separated by thin layer chromatography using hexane:methylene chloride (4:1) as eluant. Compound 4e. Yellow solid. IR (CH2Cl2, nuCO, cm-1):2076(m), 2052(s), 2040(w), 2012(vs), 1997(s), 1984(w). NMR (CDCl3): delta 1H:-21.59 (d, 3JPH=2.7 Hz, M-H-M), 0.31 (s, SiMe3), 3.56 (s, P(OMe)Ph2),7.41-7.7 (m, P(OMe)Ph2); delta 31P{H}: 119.7; delta 29Si{1H}:1.69., 4020-99-9
The synthetic route of 4020-99-9 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Gonzalez-Lopez, Vianney; Torres-Sandoval, Indira; Carrasco-Gonzalez, Ana L.; Elias-Jimenez, Adonay; Leyva, Marco A.; Rosales-Hoz, Maria J.; Cruz-Borbolla, Julian; Zuno-Cruz, Francisco J.; Sanchez-Cabrera, Gloria; Jardinez, Christian; Inorganica Chimica Acta; vol. 492; (2019); p. 8 – 17;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate