The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1608-26-0, Name is Tris(dimethylamino)phosphine
, molecular formula is P[N(CH3)2]3. In a Article，once mentioned of 1608-26-0, COA of Formula: P[N(CH3)2]3
We have investigated the reactivity of the unsymmetrical H-spirophosphorane (HSP) ligand HP(OCMe2CMe2O)(OCH2CMe 2NH) 1 towards different palladium(II) precursors and synthesised the mononuclear complexes [PdCl2{P(OCMe2CMe 2O)OCH2CMe2NH2}] 2 and [PdCl(C 3H5){P(OCMe2CMe2O)OCH 2CMe2NH2}] 3. The structural features of the compounds are characterised by spectroscopic methods as well as single crystal X-ray diffraction studies. The complexes are shown to be remarkably active precatalysts for the Heck and Hiyama cross-coupling reactions. The products of the C-C bond formation reactions were obtained with high conversion and stereoselectivity. Mechanistic studies of the Heck reaction reveal that, besides homogenous precatalysts, also heterogeneous Pd(0) nanoparticles are involved in the catalytic process.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.COA of Formula: P[N(CH3)2]3, you can also check out more blogs about1608-26-0
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate