Related Products of 1038-95-5, An article , which mentions 1038-95-5, molecular formula is C21H21P. The compound – Tri-p-tolylphosphine played an important role in people’s production and life.
The regioselectivity in the Rh catalysed 1,4-hydrosilylation of isoprene was investigated. Variation of solvents and temperature did not significantly affect the isomer distribution between tail-product (I) and head-product (II). The choice of ligands had the greater influence, where RhI-based catalysts with the strong electron withdrawing ligand CO favoured production of isomer II, while RhI catalysts with strong electron donating ligands (for example triarylphosphines) gave isomer I as the main product. In contrast to the square planar carbonyl complex RhCl(CO)(PPh3)2, the square planar thiocarbonyl complex RhCl(CS)(PPh3)2, gave I as the major isomer.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate