Application of 224311-51-7, An article , which mentions 224311-51-7, molecular formula is C20H27P. The compound – 2-(Di-tert-Butylphosphino)biphenyl played an important role in people’s production and life.
The recent progress in catalytic asymmetric carbon?boron and carbon? silicon bond formation catalyzed by chiral copper(I) complexes is tremendous. Within less than a decade, the majority of fundamental bond-forming reactions in this arena, that is, conjugate addition, 1,2-addition and allylic substitution, were accomplished. These enantioselective transformations had been either elusive or not even known before. This chapter summarizes these fascinating developments together with a brief mechanistic discussion as these copper(I) catalyses share transmetalation of interelement bonds such as B?B and Si?B as a common feature.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate