Synthetic Route of 12150-46-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 12150-46-8, C34H28FeP2. A document type is Article, introducing its new discovery.
Reactions between Ru3(mu-dppm)(CO)10 and several reagents have been studied.With allyl bromide, cluster breakup occurs to give binuclear Ru2(mu-Br)(mu-C3H5)(mu-dppm)(CO)4.With Me2S2, binuclear Ru2(mu-SMe)2(mu-dppm)(CO)4 and trinuclear Ru3(mu-H)(mu-SMe)(mu-dppm)(CO)8 are obtained; the X-ray structure of the latter has been determined.With AuCl(PPh3), addition to one Ru-Ru bond gives AuRu3(mu-Cl)(mu-dppm)(CO)8(PPh3).Some data on tertiary phosphine substituted products formed in reactions with PMe3, PPh3, P(C6H4Me-3)3, P(C6H4Me-4)3, P(OMe)3, P(OCH2CF3)3, dppe and Fe(eta-C5H4PPh2)2 are also given.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate