In an article, published in an article, once mentioned the application of 161265-03-8, Name is (9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphine),molecular formula is C39H32OP2, is a conventional compound. this article was the specific content is as follows.Recommanded Product: 161265-03-8
Developing new catalytic technologies to utilize biomass as the carbon source of chemical and material industries attracts more attention than ever because of the rapid depletion of fossil feedstock and strong societal demand. This work presents the aqueous carbonylation of bioderived 5-bromofuroic acid to afford 2,5-furandicarboxylic acid in the presence of a supported palladium catalyst. The expected 2,5-furandicarboxylic acid product was isolated in >95% yield even after reusing the catalyst 10 times. This novel protocol not only provides an alternative synthetic route to 2,5-furandicarboxylic acid complementary with the tricky 5-HMF oxidation but also offers a promising market for the underexploited hemicellulose-derived furfural platform.
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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate