Electric Literature of 131274-22-1. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 131274-22-1, Name is Tri-tert-butylphosphonium tetrafluoroborate. In a document type is Article, introducing its new discovery.
The Rh-catalyzed direct selective oxidation Heck reaction of benzamides with allylic esters has been developed for the synthesis of amides and isoquinolin-1-ones. According to the functional groups on N-atom, benzamides or isoquinolin-1-ones were synthesized under optimal reaction conditions. The ambient catalytic system has good functional group tolerance, afforded corresponding products in moderate to good yields.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate