Application of 4020-99-9. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 4020-99-9, Name is Methoxydiphenylphosphine. In a document type is Article, introducing its new discovery.
Complexes of the type PhSCo(CO)2L2 (1; L =phosphine or phosphite) and the complex MeOCS2Co(CO)2(PPh2iBu)2 (5) have been prepared from CoCl2<*>6H20, CO, the appriopriate phosphine or phosphite, and PhSH + NaOMe or MeOCS2K, respectively.The crystal structures of 1a (L =PPh2OMe) and 5<*>MeCN have been determined.These compounds are the first structurally characterized cobalt carbonyl complexes containing a monodentate thiolate or xanthate group.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate