Extended knowledge of Tris(dimethylamino)phosphine

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In an article, published in an article, once mentioned the application of 1608-26-0, Name is Tris(dimethylamino)phosphine
,molecular formula is P[N(CH3)2]3, is a conventional compound. this article was the specific content is as follows.Recommanded Product: 1608-26-0

2-Furfurylidene-. (1a) and 2-thienylidene-1,3-indandione (1b) produce the respective 1:1 adducts (8 a-f) upon reaction with the appropriate dialkyl phosphite (3 a-c). The reaction of 1a,b with trialkyl phosphite (2a-c) yield a mixture of the corresponding phosphonates (7a-d) (major) and (8a-d) (minor). Triphenylphosphine (2d) and hexamethylphosphorustriamide (2e) also reacted with 1a,b. The produced betaines (10a-c) were alkylated with methyl iodide to yield the respective phosphonium iodides (11a-d). Possible reaction mechanisms were discussed. Compatible elemental and spectroscopic results were gained for the new products.

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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate