Final Thoughts on Chemistry for 1038-95-5

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Electric Literature of 1038-95-5, An article , which mentions 1038-95-5, molecular formula is C21H21P. The compound – Tri-p-tolylphosphine played an important role in people’s production and life.

The preparation and properties of rhodium complexes of the general formulae Rh(A)(CO)2 and Rh(A)(CO)L (A=tropolone (trop), Me-trop, i-Pr-trop, salicylaldehyde (sal) are described.The coordinated salicylaldehyde moiety of (Y2=COD, (CO)2, (CO)PPh3) complexes react with primary amines to yield Rh(sal=NR)Y2 derivatives.Rh(sal=NMe)(CO)2 can be formed by addition of salicylaldehyde to the solution obtained by refluxing RhCl3*xH2O with dimethylformamide.

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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate