Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene, category: chiral-phosphine-ligands.
Nickel(II) piperidinedithiocarbamate complexes of the composition [Ni(pipdtc)(P-P)]X and [Ni2(pipdtc)2(NCS)2(dpph)] (X = NCS, ClO4, I; P-P = 1,2-bis(diphenylphosphino)ethane (dppe), 1,4-bis(diphenylphosphino)butane (dppb), 1,6-bis(diphenylphosphino)hexane (dpph), 1,4-bis(diphenylphosphino)ferrocene (dppf); pip=C5H10; dtc=S2CN-) have been synthesized. The compounds have been characterized by elemental analyses, IR, electron and 1H, 13C{1H} and 31P{1H} NMR spectroscopies, thermal analysis, magneto-chemical and conductivity measurements. A single-crystal X-ray analysis of the [Ni(pipdtc)(dppf)]ClO4 complex proved four-coordinated nickel in a deformed square-planar arrangement with a S2P2 donor set. (C) 2000 Elsevier Science Ltd.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.category: chiral-phosphine-ligands. In my other articles, you can also check out more blogs about 12150-46-8
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate