Synthetic Route of 1038-95-5. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1038-95-5, Name is Tri-p-tolylphosphine
cis-(Dimethyl)(tri-p-tolylphosphine)(ligand)platinum(II) complexes (ligand = substituted pyridine or amine) have been prepared from PtMe2(1,5-COD) (COD = cyclooctadiene), Ptol3 (tol = tolyl) and the N-donor ligand.For ligand = 4-(5-phenyl-2-oxazolyl)pyridine the crystal and molecular structure has been determined: space group R3, a = b = 43.295(5), c = 14.198(2) Angstroem (-100 deg C), gamma 120 deg, V 14459 Angstroem3, Z = 18.For 379 variables and 4977 reflections with I > 2?(I) R = 0.034, Rw = 0.042.Pt-C bond lengths are 2.082(7) (trans to P) and 2.059(8) Anstroem (trans to N).Amine ligands are displaced by ethylene to form an unstable ethylene adduct.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate