Electric Literature of 5931-53-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 5931-53-3, Name is Diphenyl(o-tolyl)phosphine. In a document type is Article, introducing its new discovery.
The possibility of cross coupling of organic halides and chlorophosphines under the action of electrochemically generated Ni(0) complexes of 2,2?-bipy is shown. The final triorganylphosphines are formed by several pathways, including reaction of the sigma complex of ArNiX with chlorophosphine and electron transfer-induced reductive elimination of Ph2PArNiX, leading to the cross-coupling product.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate