Related Products of 1038-95-5. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 1038-95-5, Name is Tri-p-tolylphosphine. In a document type is Article, introducing its new discovery.
(R3P)2PtCl2 and C2H4 yield the compounds [{eta2-C2H4}Pt(PR3)2] (PR3 = PMe3, PEt3, PPhEt2, PPh2Et, PPh2Me, PPh2iPr, PPh2tBu and P(p-Tol)3); which react with tBu2P-P=PMetBu2 to give the phosphinophosphinidene complexes [{eta2-tBu2P-P}Pt(PMe3) 2], [{eta2-tBu2P-P}Pt(PEt3) 2], [{eta2-tBu2P-P}Pt(PPhEt2) 2], [{eta2-tBu2P-P}Pt(PPh2Et) 2], [{eta2-tBu2P-P}Pt(PPh2Me) 2], [{eta2-tBu2P-P}Pt(PPh2 iPr], [{eta2-tBu2P-P}Pt(PPh2 tBu)2] and [{eta2-tBu2P-P}Pt(P(p-Tol)3) 2]. [{eta2-tBu2P-P}Pt(PPh3) 2] reacts with PMe3 and PEt3 as well as with tBu2PMe, PiPr3 and P(c-Hex)3 by substituting one PPh3 ligand to give [{eta2-tBu2P1-P 2}Pt(P3Me3)(P4Ph3)], [{eta2-tBu2P1-P 2}Pt(P3Ph3)(P4Me3)], [{eta2-tBu2P1-P 2}Pt(P3Et3)(P4Ph3)], [{eta2-tBu2P1-P 2}Pt(P3MetBu2)(P4Ph 3)], [{eta2-tBu2P1-P 2}Pt(P3iPr3)(P4Ph3)] and [{eta2-tBu2P1-P 2}Pt(P3(c-Hex)3)(P4Ph3)]. With tBu2PMe, [{eta2-tBu2P-P}Pt(P(p-Tol)3) 2] forms [{eta2-tBu2P1-P 2}Pt(P3MetBu2)(P 4(p-Tol)3)]. The NMR data of the compounds are given and discussed with respect to the influence of the PR3 ligands.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate