In an article, published in an article, once mentioned the application of 1038-95-5, Name is Tri-p-tolylphosphine,molecular formula is C21H21P, is a conventional compound. this article was the specific content is as follows.Computed Properties of C21H21P
Selective palladium diacetate-catalyzed alpha- and beta-arylations of the furan rings of (ortho-bromophenyl)furan-2-yl-methanones 1 under two different conditions are reported. In the presence of potassium tert-butoxide as a strong base and triphenylphosphine as a ligand, methanones 1 undergo alpha-arylation accompanied by C(CO)-C bond cleavage. In contrast, in the presence of potassium carbonate as the base and tricyclohexylphosphonium tetrafluoroborate as the ligand, methanones 1 undergo intramolecular beta-arylation to afford furan-derived fluorenones in high yields from a wide variety of substrates. In addition, a one-pot protocol for the successive direct intramolecular beta-arylation and intermolecular alpha-arylation of the furan rings of 1 has been achieved.
Do you like my blog? If you like, you can also browse other articles about this kind. Computed Properties of C21H21P. Thanks for taking the time to read the blog about 1038-95-5
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate