The important role of 2-(Di-tert-Butylphosphino)biphenyl

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Related Products of 224311-51-7. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 224311-51-7, Name is 2-(Di-tert-Butylphosphino)biphenyl

The reaction of bis(diphenylphosphino)acetylene(DPPA) with Co2(CO)8 in toluene at 80 C for 24 h resulted in an alkyne-bridged, diphosphine-chelated tetracobalt-complex, [Co2(CO)5{mu-P,P- (mu-PPh2C?CPPh2)}] [Co2(CO)4{mu-P- (mu-PPh2C?CPPh2)}] 3. The X-ray structural studies of 3 reveals that it can be regarded as a dimerized form of two DPPA bridged dicobalt complex, [Co2(CO)6 (mu-PPh2C?CPPh2)] 1.

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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate