A new application about 2-(Diphenylphosphino)benzaldehyde

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The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.50777-76-9, Name is 2-(Diphenylphosphino)benzaldehyde, molecular formula is C19H15OP. In a Article,once mentioned of 50777-76-9, Recommanded Product: 50777-76-9

Treating C60 with o-(diphenylphosphino)benzaldehyde and o-aminomethylpyridine in refluxing o-dichlorobenzene affords a new fullerene derivative syn-PPh2(o-C6H4)(o-C5H4N)(C2H3NC60) (1) in moderate yield. Compound 1 displays versatile coordination modes. Such that, reactions of 1 with Os3(CO)11(NCMe), W(CO)4(NCMe)2, and Ru3(CO)12 produce Os3(CO)11(eta1-PPh2(o-C6H4)(o-C5H4N)(C2H3NC60)) (2), W(CO)4(eta2-PPh2(o-C6H4)(o-C5H4N)(C2H3NC60)) (3), and Ru(CO)3(eta3-PPh2(o-C6H4)(o-C5H4N)(C2H3NC60)) (4), respectively. Interestingly, heating 4 with Ru3(CO)12 leads to transfer of the fullerene addend to give C60 and a tetraruthenium cluster complex (mu-H)Ru4(CO)11(mu4,eta4-PPh2(o-C6H4)CH2NC(o-C5H4N)) (5). The structures of 1 and 5 have been determined by an X-ray diffraction study.

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Recommanded Product: 50777-76-9, you can also check out more blogs about50777-76-9

Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate