Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 224311-51-7, Name is 2-(Di-tert-Butylphosphino)biphenyl, Application In Synthesis of 2-(Di-tert-Butylphosphino)biphenyl.
Synthetic nitrogen fixation with mononuclear molybdenum(0) phosphine complexes: Occupying the trans-position of coordinated N2
Synthetic nitrogen fixation with molybdenum phosphine complexes has witnessed a renaissance recently due to the discovery that such systems are competent to catalytically convert N2 to ammonia. In the framework of this research area, we have prepared complexes of the type [Mo(N2)(PEP)(P2)] (E = N, P; P2 = dppm, dmpm) in which the linear PEP ligand coordinates in a facial geometry. Similar complexes have been prepared using mixed carbene?phosphine (PCP) ligands. Furthermore, molybdenum bis(dinitrogen) complexes have been synthesized which are facially coordinated by a tripod ligand and contain the bidentate coligands dppm and dmpm. Recently, both of these approaches have been united in the synthesis of a Mo(0)?N2 complex supported by a pentadentate tetrapodal (pentaPod) ligand. The structural, electronic, and vibrational properties of all of these dinitrogen complexes have been investigated by NMR, IR, and Raman spectroscopy, and their reactivities in a nitrogen fixing cycle have been evaluated. To this end, protonated derivatives have been investigated as well. On the basis of these results and DFT calculations, these systems are promising candidates for the catalytic conversion of N2 to ammonia.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Application In Synthesis of 2-(Di-tert-Butylphosphino)biphenyl. In my other articles, you can also check out more blogs about 224311-51-7
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate