224311-51-7, Name is 2-(Di-tert-Butylphosphino)biphenyl, molecular formula is C20H27P, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 224311-51-7, Application In Synthesis of 2-(Di-tert-Butylphosphino)biphenyl
Synthesis and reactivity of (phosphinoaklyl)silyl complexes
Silyl ancillary ligands are expected to generate the reactive unsaturated metal center due to their exceptionally strong trans-influence and -effect. Nevertheless, little has been known on the influence of silyl ligands on the reactivity of transition-metal complexes. This would be mainly due to the facile cleavage of the metal-silicon bond. (Phosphinoalkyl)silyl ligands have been developed to suppress the elimination of silyl groups from the metal center. This article reviews the synthesis and properties of the transition metal complexes having chelate-type (phosphinoalkyl)silyl ligands R2P(CH2)nSiR2 (n = 1, 2).
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Application In Synthesis of 2-(Di-tert-Butylphosphino)biphenyl. In my other articles, you can also check out more blogs about 224311-51-7
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate