Reference of 50777-76-9. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 50777-76-9, Name is 2-(Diphenylphosphino)benzaldehyde
A palladium(II) complex of a new iminophosphine ligand derived from diethylenetriamine and 2-(diphenylphosphino)benzaldehyde
The mononuclear complexes [Pd(oPdien)]X2 {oPdien = N-(2-diphenylphosphinobenzylidene)diethylenetriamine: (4a) X2 = [ZnCl4]2-; (4b) X = [PF6]-; (4c) X = Cl-} are described. Complex 4a formed in high yield when [Pd(oPCHO)2Cl2] [oPCHO = 2-(diphenylphosphino)benzaldehyde] (1) and [Zn(dien)Cl2] (2) were reacted together in an unsuccessful attempt to template formation of a bimetallic iminophosphine-bridged complex. The X-ray crystal structure of 4b has been determined. The ligand oPdien is the first iminophosphine derived from dien and has been isolated and used to prepare 4c. (C) 2000 Elsevier Science S.A.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate