Application of 50777-76-9. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 50777-76-9, Name is 2-(Diphenylphosphino)benzaldehyde. In a document type is Article, introducing its new discovery.
Palladium-catalyzed asymmetric allylic substitution of 1,3-diphenyl-2- propenyl acetate (3) with a dimethyl malonate-BSA-LiOAc system and its derivatives has been successfully carried out in the presence of a new chiral hydrazone ligand 2-diphenylphosphinobenzaldehyde SAMP hydrazone (DPPB-SAMP) (2) in high yields with high enantioselectives (up to 92% ee).
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate