7650-91-1, Name is Benzyldiphenylphosphine, molecular formula is C19H17P, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 7650-91-1, Formula: C19H17P
Readily available air- and moisture-stable dimeric chloro-bridged CN-, CS- and CP-cyclopalladated complexes with the (sp2)C-Pd bond react with 4.5 equiv. of KPPh2 in THF to give the corresponding P,N-, P,S- and P,P-bidentate ligands in 35-63% yield. The phosphination method is applicable to five- and six-membered palladacycles derived from (S)-N,N-dimethyl-1- phenylethylamine, (S)-4-tert-butyl-2-phenyl-2-oxazoline, benzyl methyl sulfide, benzyldiphenylphosphine, 2-benzylpyridine and N,N-dimethylbiphenyl-2-amine. The reaction of 1.2 equiv. of KPPh2 with the SCS-pincer cyclopalladated complex obtained from 1,3-bis(methylthiomethyl)benzene provided the corresponding S,P,S-tridentate ligand in 49% yield.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: C19H17P. In my other articles, you can also check out more blogs about 7650-91-1
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate