The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 6372-42-5, Name is Cyclohexyldiphenylphosphine, SMILES is C1CCC(CC1)P(C1=CC=CC=C1)C1=CC=CC=C1, in an article , author is Yang, Zhiping, once mentioned of 6372-42-5, Application In Synthesis of Cyclohexyldiphenylphosphine.
Palladium-catalyzed asymmetric hydrophosphorylation of alkynes: facile access toP-stereogenic phosphinates
Despite the importance ofP-chiral organophosphorus compounds in asymmetric catalysis, transition metal-catalyzed methods for accessingP-chiral phosphine derivatives are still limited. Herein, a catalytic enantioselective method for the synthesis ofP-stereogenic alkenylphosphinates is developed through asymmetric hydrophosphorylation of alkynes. This process is demonstrated for a wide range of racemic phosphinates and leads to diverseP-stereogenic alkenylphosphinates directly.
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Reference:
Phosphine ligand,
,Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate