Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of P[N(CH3)2]3. In my other articles, you can also check out more blogs about 1608-26-0
1608-26-0, Name is Tris(dimethylamino)phosphine
, molecular formula is P[N(CH3)2]3, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 1608-26-0, Computed Properties of P[N(CH3)2]3
Photochemische Aren-Substitution in Cyclopentadienyleisen-Aren-Kationen-Eine allgemeine Synthese fuer Cyclopentadienyleisen-Bisphosphin-Ligand-Komplexe mit Liganden der 4. und 5. Hauptgruppe
PF6 undergoes photochemical p-xylene substitution in nitrile (RCN) solution in the presence of two equivalents of phosphorus donor ligands L upon UV-vis irradiation at lambdamax<*>300 nm (R = CH3, C2H5, n-C3H7; L = P(OCH3)3 or 1/2<(C6H5)2PCH2>2).High yields of NCR>PF6 complexes are obtained.Thermal substitution of the coordinated nitrile ligand RCN in these complexes in the presence of group 14 and 15 donor ligands L’ affords good yields of PF6 compounds.Selected reactions of these complexes are discussed.Based on 1H, 13C, and 31P NMR data and by comparison with those of related X complexes, a decreasing electron density on the C5H5Fe+ center is concluded in the order for L2 = <(C6H5)2PCH2>2 > (P(OCH3)3)2 > (CO)2.The molecular structures of three complexes PF6 with L’ = NCCH3, P(OCH3)3 and Sb(C6H5)3 were obtained by single-crystal X-ray structure determination and discussed.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of P[N(CH3)2]3. In my other articles, you can also check out more blogs about 1608-26-0
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate