Application of 224311-51-7. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 224311-51-7, Name is 2-(Di-tert-Butylphosphino)biphenyl. In a document type is Review, introducing its new discovery.
Enantioselective C?H Bond Functionalizations by 3d Transition-Metal Catalysts
Direct catalytic modifications of carbon?hydrogen (C?H) bonds, ubiquitous in organic molecules, represent a powerful strategy in organic synthesis. In the past decade, chemists have focused on the development of sustainable methods for functionalization of inert C?H bonds using cost-effective earth-abundant 3d transition-metal catalysts. To fully harness the potential of this technology, however, it is essential to control the stereoselectivity of the C?H functionalization processes. This review describes developments in the emerging area of enantioselective functionalization of C?H bonds by 3d transition-metal catalysts proceeding via inner-sphere C?H activation.
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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate