4020-99-9, Name is Methoxydiphenylphosphine, molecular formula is C13H13OP, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 4020-99-9, COA of Formula: C13H13OP
CO substitution vs C[sbnd]Si cleavage in the reactions of [(mu-H)M3(CO)9(CCSiR3)] (M?=?Ru, R?=?Me, Ph; M?=?Os, R?=?Me) with tertiary phosphines: Experimental and theoretical studies
This work describes the reactions of [(mu-H)M3(CO)9(CCSiMe3)] (M = Ru, Os) with phosphines L (L = PMe3, PMe2Ph, PMePh2, and PPh3) which produce zwitterionic compounds [(mu-H)M3(CO)9(HCCPR3)] where cleavage of the C[sbnd]Si and formation of C[sbnd]P bonds occurs. In the case of the ruthenium derivatives, CO substitution also occurs. Spectroscopic and structural characterization of the products is described. A theoretical analysis was carried out in order to understand the transformation pathway in the formation of the zwitterionic compounds.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.COA of Formula: C13H13OP. In my other articles, you can also check out more blogs about 4020-99-9
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate