A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 97239-80-0, Name is 1,1′-Bis(diisopropylphosphino)ferrocene, molecular formula is C22H28FeP2. In a Article£¬once mentioned of 97239-80-0, category: chiral-phosphine-ligands
Iron(II) versus osmium(II) oxidation in 1,1?-bis(diorganophosphino)ferrocene-osmium(II) complexes
The compounds [(Cym)OsCl(dxpf)](PF6), Cym=p-cymene and dxpf: 1,1?-bis(diphenylphosphino)ferrocene (dppf), 1,1?-bis(diethylphosphino)ferrocene (depf) or 1,1?-bis(diisopropylphosphino)ferrocene (dippf), were synthesized and characterized by NMR (1H, 31P) and, in the case of [(Cym)OsCl(dppf)](PF6), by X-ray structure analysis of the acetonitrile solvate. EPR and UV-vis spectroelectrochemistry indicate the formation of an osmium(II)-ferrocenium species on reversible one-electron oxidation. The second oxidation and the reduction are electrochemically irreversible.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.category: chiral-phosphine-ligands. In my other articles, you can also check out more blogs about 97239-80-0
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate