Reference of 84127-04-8. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 84127-04-8, Name is Bis(4-methoxyphenyl)phosphine. In a document type is Article, introducing its new discovery.
Dehydrocoupling of phosphanes catalyzed by a rhodium(I) complex
Two reaction protocols have been developed for the catalytic dehydrocoupling of secondary phosphanes by the rhodium(I) complex [Cp*Rh{CH2=CH(TMS)}2]: In the presence of an olefin, transfer hydrogenation occurs to give the corresponding alkane and the diphosphane. Without the addition of an olefin, the reaction proceeds by loss of dihydrogen but more elevated reaction temperatures must be used [Eq. (1)].
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate