Electric Literature of 1608-26-0. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1608-26-0, Name is Tris(dimethylamino)phosphine
ON DERIVATISATION REACTIONS OF 2-CHLORO-3-DICHLOROPHOSPHANYL-1-METHYL-1.3.2-DIAZAPHOSPHORINANE
Derivatisation reactions of 2-chloro-3-dichlorophosphanyl-1-methyl-1.3.2-diazaphosphorinane 1 with protic nucleophiles like HNEt2, CH3OH, C2H5OH and the Franz-reagent NEt3HF forming the substituted N-phosphanyldiazaphosphorinanes 2-12 are described.The preferential nucleophilic attack on the exocyclic phosphanyl group of 1 in partial replacement reactions is discussed by means of 31P-, 1H- and 13C-NMR data.Key words: 2-Chloro-3-dichlorophosphanyl-1-methyl-1.3.2-diazaphosphorinane; N-phosphanyldiazaphosphorinanes, NMR-data.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate