Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn¡¯t involve a screen. 1608-26-0, P[N(CH3)2]3. A document type is Article, introducing its new discovery., name: Tris(dimethylamino)phosphine
Rhenium catalyzed sulfurization of phosphorus(III) compounds with thiiranes: New reagents for phosphorothioate ester synthesis
A new method for the mild sulfurization of phosphorus(III) compounds with thiiranes catalyzed by ReOCl3(PPh3)2 (I) or ReOCl3(SMe2)OPPh3) (II) is reported. The novel catalytic sulfur transfer reactions are rapid and occur efficiently under ambient conditions in organic solvents. This methodology enabled propylene sulfide to be used as a sulfurizing agent for the synthesis of a protected nucleotide phosphorothioate ester.
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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate