19845-69-3, Name is 1,6-Bis(diphenylphosphino)hexane, molecular formula is C30H32P2, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 19845-69-3, COA of Formula: C30H32P2
The synthesis of novel neutral mononuclear ruthenium fragments for cluster capping reactions and their reactivity
The mononuclear complex [Ru(CO)4(C2H4)] (1) reacts with bidentate phosphines to yield the corresponding [Ru(CO)4(eta1-bidentate phosphine)] (3) complex in quantitative yield thereby offering a new route to this class of compound. Broadband UV photolysis of dichloromethane solutions of the 1,2-bis(diphenylphosphino)propane (dppp) complex [Ru(CO)4(eta1-dppp)] (3d) under an atmosphere of ethene yields the di-substituted complex [Ru(CO)3(eta1-dppp)(eta2-C2H4)] (9d) in quantitative yield. Both 3d and 9d show potential in selective cluster capping reactions as illustrated by their reactivity with [Ru5C(CO)15] (4) and [Ru3(CO)12] (2).
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.COA of Formula: C30H32P2. In my other articles, you can also check out more blogs about 19845-69-3
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate