Trost, Barry M.; Tsui, Hon-Chung; Toste, F. Dean published the artcile< Deracemization of Baylis-Hillman Adducts>, Product Details of C54H42N2O2P2, the main research area is deracemization Baylis Hillman adduct.
Pd2dba3 in presence of a chiral ligand catalyzed the reaction of phenols with carbonates of Baylis-Hillman adducts RCH(OCO2Me)C(EWG):CH2 (I; R = Pr, PhCH2CH2, etc.; EWG = CN, CO2Et).
Journal of the American Chemical Society published new progress about Racemization. 152140-65-3 belongs to class chiral-phosphine-ligands, and the molecular formula is C54H42N2O2P2, Product Details of C54H42N2O2P2.
Referemce:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate