Cera, Gianpiero; Chiarucci, Michel; Mazzanti, Andrea; Mancinelli, Michele; Bandini, Marco published the artcile< Enantioselective gold-catalyzed synthesis of polycyclic indolines>, Quality Control of 325168-88-5, the main research area is furoindoline enantioselective preparation; dihydropyranylindoline enantioselective preparation; hydroxyalkynylindole preparation intramol cyclization gold catalyst.
The synthesis of architecturally complex polycyclic fused indolines is achieved in a chemo-, regio-, and stereodefined manner, via an enantioselective gold-catalyzed cascade hydroindolination/iminium trapping synthetic sequence. Highly functionalized tetracyclic fused furoindolines and dihydropyranylindolines are synthesized in moderate to good yields and enantiomeric excesses of up to 87%.
Organic Letters published new progress about Chiral ligands Role: CAT (Catalyst Use), USES (Uses). 325168-88-5 belongs to class chiral-phosphine-ligands, and the molecular formula is C48H50P2, Quality Control of 325168-88-5.
Referemce:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate