Tsukamoto, Hirokazu; Suzuki, Risako; Kondo, Yoshinori published the artcile< Revisiting Benzenesulfonyl Linker for the Deoxygenation and Multifunctionalization of Phenols>, Computed Properties of 277306-29-3, the main research area is arene preparation solid phase; aryl amine thioether cycloheptanone preparation solid phase; biaryl preparation solid phase; reductive cleavage resin bound aryl sulfonate palladium catalyst; coupling reaction resin bound aryl sulfonate palladium nickel catalyst; benzenesulfonyl linker deoxygenation functionalization phenol derivative preparation; benzenesulfonic benzenesulfonyl linker deoxygenation functionalization phenol derivative preparation.
Arenes are prepared by sulfonylation of phenols with a resin-bound benzenesulfonyl chloride followed by palladium- and nickel-catalyzed reductive cleavage and coupling reactions to yield arenes, benzamides, aryl amines, biaryls, aryl thioethers, and an arylcycloheptanone. The effect of changes of ligand and palladium catalyst on the palladium-catalyzed reductive cleavage of 4-tosyloxyacetanilide to acetanilide is studied as a test case for the solid-phase reductive cleavage reactions.
Journal of Combinatorial Chemistry published new progress about Aromatic hydrocarbons Role: SPN (Synthetic Preparation), PREP (Preparation). 277306-29-3 belongs to class chiral-phosphine-ligands, and the molecular formula is C32H40FeP2, Computed Properties of 277306-29-3.
Referemce:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate