Tsui, Gavin C.; Lautens, Mark published the artcile< Rhodium(I)-Catalyzed Domino Asymmetric Ring Opening/Enantioselective Isomerization of Oxabicyclic Alkenes with Water>, Application of C32H40FeP2, the main research area is rhodium catalyzed domino asym ring opening isomerization oxabicycloalkene water; hydroxytetralone enantioselective preparation.
Enantio-enriched 2-hydroxy-1-tetralones are formed from oxabicyclic alkenes through a novel RhI-catalyzed domino reaction. The proposed mechanism involves water-induced asym. ring opening to generate chiral trans-1,2-diol intermediates and subsequent enantioselective isomerization (I → II → III).
Angewandte Chemie, International Edition published new progress about Bicyclic compounds Role: RCT (Reactant), RACT (Reactant or Reagent). 277306-29-3 belongs to class chiral-phosphine-ligands, and the molecular formula is C32H40FeP2, Application of C32H40FeP2.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate