Ludvik, J.; Volke, J. published the artcile< Evidence for a radical intermediate in the anodic oxidation of reduced nicotinamide adenine dinucleotides obtained by electrogenerated chemiluminescence>, Category: chiral-phosphine-ligands, the main research area is electrooxidation product reduction nicotinamide adenine dinucleotide; adenine derivative electrochemiluminescence; chemiluminescence adenine derivative; radical intermediate redox reaction adenine derivative.
Electrogenerated chemiluminescence is used to show that the radicals NAD• and NADP• are intermediates in the electrooxidation of NADH and NADPH at a Pt anode in anhydrous or partly aqueous (up to 15 volume%) DMSO. An ECE mechanism seems to predominate. The use of DMSO proved to be very convenient, with the advantage of enabling electrogenerated chemiluminescence to be obtained in partly aqueous media even with ionic substances as substrates. The method is useful in proving the existence of unstable radical intermediates in redox processes, even for relatively large mols. such as NADH and NADPH.
Analytica Chimica Acta published new progress about Adsorption. 606-68-8 belongs to class chiral-phosphine-ligands, and the molecular formula is C21H27N7Na2O14P2, Category: chiral-phosphine-ligands.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate