Lipshutz, Bruce H.; Servesko, Jeff M. published the artcile< CuH-catalyzed asymmetric conjugate reductions of acyclic enones>, SDS of cas: 277306-29-3, the main research area is enone conjugate copper catalyzed stereoselective reduction; alkanone asym synthesis.
A CuH-catalyzed asym. conjugate reduction of acyclic enones is reported. The reduction of enones was carried out with a catalytic amount of triphenylphosphine-copper hydride, in the presence of a chiral ligand, to afford alkanones, e.g. I, in high yields and enantiomeric excess.
Angewandte Chemie, International Edition published new progress about Aliphatic ketones Role: SPN (Synthetic Preparation), PREP (Preparation). 277306-29-3 belongs to class chiral-phosphine-ligands, and the molecular formula is C32H40FeP2, SDS of cas: 277306-29-3.
Referemce:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate