Tang, Liang L.; Ryabov, Alexander D.; Collins, Terrence J. published the artcile< Kinetic Evidence for Reactive Dimeric TAML Iron Species in the Catalytic Oxidation of NADH and a Dye by O2 in AOT Reverse Micelles>, Application of C21H27N7Na2O14P2, the main research area is kinetics reactive dimeric TAML iron species; catalytic oxidation NADH dye oxygen AOT reverse micelle.
The efficacy of the iron(III) TAML activator [Fe{C6H4-1,2-(N1COCMe2N2CO)2CMe2(Fe-N1)(Fe-N2)}(OH2)]- (1) for the catalytic activation of dioxygen in reverse micelles of Aerosol OT (AOT) in n-octane has been studied. Kinetic evidence is presented for the existence of unusual second-order catalytic pathways in the oxidation of NADH to NAD+ and the bleaching of blue pinacyanol chloride (PNC) dye. Depending on the substrate and reaction conditions, a second-order pathway in [1] either dominates or proceeds in obvious combination with a first-order pathway in [1]. Detailed kinetic anal. of the exptl. data supports the previously made hypothesis that the reactive intermediate is associated with the mixed-valent dimer system [LFeIIIOFeIVL]3-/[LFeIII(OH)FeIVL]2-.
ACS Catalysis published new progress about Bleaching. 606-68-8 belongs to class chiral-phosphine-ligands, and the molecular formula is C21H27N7Na2O14P2, Application of C21H27N7Na2O14P2.
Referemce:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate